Introduction-Role of Thermodynamics in Engineering and Science-Applications of Thermodynamics – Macroscopic and Microscopic Analysis-Thermodynamic System and Control Volume-Thermodynamic Properties, Processes and Cycles- Thermodynamic Equilibrium- concept of continuum- Quasi static process- Heat and work transfer- Sign Convention -Displacement work and other modes of work - P-V diagram -The Zeroth Law of Thermodynamics- First Law of Thermodynamics

Second law of Thermodynamics-Heat Reservoir-source and sink -Refrigerator and heat pump- - Statements of second law and its corollaries-Carnot theorem & Carnot Corollaries-Reversible & Irreversible Process Entropy-Concept of Entropy- Entropy-A Property of a System- Clausius Inequality-principle of increase in entropy different processes – Entropy & Reversibility-Entropy Change in Reversible Process –Exergy Analysis

Formation of steam and its thermodynamic properties, - P-V, P-T, T-V, T-s & h-s , P -V-T surface - Use of Steam Table and Mollier Chart - Determination of dryness fraction- Application of I & II law for pure substances

Air-standard Power Cycles-Concept, Carnot vapor Cycle, Rankine Cycle-Effect of operating Variables on Rankine Cycle performance-The Reheat Rankine Cycle- The Regenerative Cycle

Mole and Mass fraction - Dalton’s. Properties of gas mixture -Molar mass - gas constant - density. Properties of Ideal gas - Ideal and real gas comparison - Equations of state for ideal and real Gases - Reduced Properties - Compressibility Factor - Maxwell relations - Tds Equations - Difference and ratio of heat Capacities - Energy Equation -Joule Thomson Coefficient -Clausius Clapeyron equation and its applications.